| 27 Jun 23 | r06     | San LorenzoSan Lorenzo | 4 - 1 | Estudiantes de Mérida F.CEstudiantes d |
| 27 Jun 23 | r06 | PalestinoPalestino | 1 - 2 | FortalezaFortaleza |
| 28 Jun 23 | r06 | Sao PauloSao Paulo | 2 - 0 | TigreTigre |
| 28 Jun 23 | r06 | Deportes TolimaDeportes Toli | 3 - 1 | Puerto Cabello F.C.Puerto Cabell |
| 28 Jun 23 | r06 | Estudiantes de la PlataEstudiantes d | 4 - 0 | Oriente PetroleroOriente Petro |
| 28 Jun 23 | r06 | BragantinoBragantino | 7 - 1 | TacuaryTacuary |
| 29 Jun 23 | r06 | EmelecEmelec | 2 - 1 | DanubioDanubio |
| 29 Jun 23 | r06 | Club GuaraníClub Guaraní | 2 - 0 | HuracanHuracan |
| 29 Jun 23 | r06 | Independiente Santa FeIndependiente | 1 - 2 | GoiasGoias |
| 29 Jun 23 | r06 | UniversitarioUniversitario | 1 - 0 | Gimnasia LPGimnasia LP |
| 29 Jun 23 | r06 | Santos FCSantos FC | 0 - 0 | BloomingBlooming |
| 29 Jun 23 | r06 | Newells Old BoysNewells Old B | 1 - 1 | Audax ItalianoAudax Italian |
| 30 Jun 23 | r06 | PeñarolPeñarol | 1 - 2 | America MGAmerica MG |
| 30 Jun 23 | r06 | Defensa y JusticiaDefensa y Jus | 3 - 1 | Millonarios F.C.Millonarios F |
| 30 Jun 23 | r06 | LDU QuitoLDU Quito | 3 - 0 | Universidad César VallejoUniversidad C |
| 30 Jun 23 | r06 | Botafogo RJBotafogo RJ | 1 - 1 | MagallanesMagallanes |
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