| 02 May 23 | r03     | Deportes TolimaDeportes Toli | 0 - 0 | Sao PauloSao Paulo |
| 02 May 23 | r03 | TacuaryTacuary | 3 - 1 | Oriente PetroleroOriente Petro |
| 02 May 23 | r03 | HuracanHuracan | 1 - 1 | DanubioDanubio |
| 03 May 23 | r03 | MagallanesMagallanes | 2 - 2 | Universidad César VallejoUniversidad C |
| 03 May 23 | r03 | BragantinoBragantino | 0 - 0 | Estudiantes de la PlataEstudiantes d |
| 03 May 23 | r03 | Newells Old BoysNewells Old B | 1 - 0 | Santos FCSantos FC |
| 03 May 23 | r03 | PalestinoPalestino | 0 - 0 | San LorenzoSan Lorenzo |
| 04 May 23 | r03 | Club GuaraníClub Guaraní | 1 - 1 | EmelecEmelec |
| 04 May 23 | r03 | Puerto Cabello F.C.Puerto Cabell | 0 - 3 | TigreTigre |
| 04 May 23 | r03 | Millonarios F.C.Millonarios F | 1 - 1 | America MGAmerica MG |
| 04 May 23 | r03 | Gimnasia LPGimnasia LP | 0 - 2 | GoiasGoias |
| 05 May 23 | r03 | FortalezaFortaleza | 6 - 1 | Estudiantes de Mérida F.CEstudiantes d |
| 05 May 23 | r03 | Botafogo RJBotafogo RJ | 0 - 0 | LDU QuitoLDU Quito |
| 05 May 23 | r03 | Defensa y JusticiaDefensa y Jus | 4 - 1 | PeñarolPeñarol |
| 05 May 23 | r03 | Audax ItalianoAudax Italian | 2 - 0 | BloomingBlooming |
| 05 May 23 | r03 | UniversitarioUniversitario | 2 - 0 | Independiente Santa FeIndependiente |
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