| 18 Apr 23 | r02     | BragantinoBragantino | 5 - 0 | Oriente PetroleroOriente Petro |
| 18 Apr 23 | r02 | Newells Old BoysNewells Old B | 3 - 0 | BloomingBlooming |
| 19 Apr 23 | r02 | Estudiantes de la PlataEstudiantes d | 4 - 0 | TacuaryTacuary |
| 19 Apr 23 | r02 | PalestinoPalestino | 1 - 0 | Estudiantes de Mérida F.CEstudiantes d |
| 19 Apr 23 | r02 | Sao PauloSao Paulo | 2 - 0 | Puerto Cabello F.C.Puerto Cabell |
| 19 Apr 23 | r02 | Independiente Santa FeIndependiente | 2 - 1 | Gimnasia LPGimnasia LP |
| 19 Apr 23 | r02 | Club GuaraníClub Guaraní | 2 - 1 | DanubioDanubio |
| 20 Apr 23 | r02 | Defensa y JusticiaDefensa y Jus | 2 - 1 | America MGAmerica MG |
| 20 Apr 23 | r02 | LDU QuitoLDU Quito | 4 - 0 | MagallanesMagallanes |
| 20 Apr 23 | r02 | San LorenzoSan Lorenzo | 0 - 2 | FortalezaFortaleza |
| 20 Apr 23 | r02 | Santos FCSantos FC | 0 - 0 | Audax ItalianoAudax Italian |
| 20 Apr 23 | r02 | PeñarolPeñarol | 0 - 2 | Millonarios F.C.Millonarios F |
| 21 Apr 23 | r02 | Botafogo RJBotafogo RJ | 4 - 0 | Universidad César VallejoUniversidad C |
| 21 Apr 23 | r02 | UniversitarioUniversitario | 2 - 2 | GoiasGoias |
| 21 Apr 23 | r02 | EmelecEmelec | 1 - 0 | HuracanHuracan |
| 21 Apr 23 | r02 | Deportes TolimaDeportes Toli | 1 - 2 | TigreTigre |
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