| 28 Aug 21 | r01  | San Fernando CDSan Fernando | 1 - 3 | Villarreal BVillarreal B |
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| 05 Sep 21 | r02  | Villarreal BVillarreal B | 3 - 0 | CornellàCornellà |
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| 12 Sep 21 | r03 | Atlético BalearesAtlético Bale | 0 - 0 | Villarreal BVillarreal B |
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| 18 Sep 21 | r04 | Villarreal BVillarreal B | 3 - 0 | AlbaceteAlbacete |
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| 26 Sep 21 | r05 | Villarreal BVillarreal B | 2 - 0 | LlagosteraLlagostera |
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| 01 Oct 21 | r06 | SabadellSabadell | 0 - 1 | Villarreal BVillarreal B |
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| 10 Oct 21 | r07 | Villarreal BVillarreal B | 5 - 1 | Sevilla AtleticoSevilla Atlet |
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| 16 Oct 21 | r08 | Betis DeportivoBetis Deporti | 1 - 2 | Villarreal BVillarreal B |
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| 23 Oct 21 | r09 | Villarreal BVillarreal B | 2 - 0 | FC AndorraFC Andorra |
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| 29 Oct 21 | r10 | Real Madrid BReal Madrid B | 2 - 1 | Villarreal BVillarreal B |
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| 07 Nov 21 | r11 | Villarreal BVillarreal B | 0 - 1 | AlcoyanoAlcoyano |
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| 13 Nov 21 | r12 | Linares DeportivoLinares Depor | 2 - 1 | Villarreal BVillarreal B |
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| 27 Nov 21 | r14 | LinenseLinense | 1 - 2 | Villarreal BVillarreal B |
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| 05 Dec 21 | r15 | Villarreal BVillarreal B | 3 - 0 | Barcelona BBarcelona B |
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| 12 Dec 21 | r16 | GimnasticGimnastic | 1 - 0 | Villarreal BVillarreal B |
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| 17 Dec 21 | r17 | Villarreal BVillarreal B | 2 - 1 | UCAM MurciaUCAM Murcia |
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| 09 Jan 22 | r18 | Algeciras CFAlgeciras CF | 2 - 1 | Villarreal BVillarreal B |
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| 18 Jan 22 | r13 | Villarreal BVillarreal B | 3 - 2 | CastellónCastellón |
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| 23 Jan 22 | r19 | Villarreal BVillarreal B | 4 - 1 | Atlético SanluqueñoAtlético Sanl |
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| 26 Jan 22 | r20 | Sevilla AtleticoSevilla Atlet | 2 - 1 | Villarreal BVillarreal B |
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| 29 Jan 22 | r21 | Villarreal BVillarreal B | 0 - 3 | San Fernando CDSan Fernando |
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| 13 Feb 22 | r23 | FC AndorraFC Andorra | 0 - 1 | Villarreal BVillarreal B |
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| 19 Feb 22 | r24 | Villarreal BVillarreal B | 3 - 0 | Betis DeportivoBetis Deporti |
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| 26 Feb 22 | r25 | AlbaceteAlbacete | 1 - 0 | Villarreal BVillarreal B |
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| 05 Mar 22 | r26 | Villarreal BVillarreal B | 0 - 3 | SabadellSabadell |
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| 09 Mar 22 | r22 | LlagosteraLlagostera | 0 - 0 | Villarreal BVillarreal B |
| |
| 13 Mar 22 | r27 | UCAM MurciaUCAM Murcia | 2 - 3 | Villarreal BVillarreal B |
| |
| 18 Mar 22 | r28 | Villarreal BVillarreal B | 0 - 0 | GimnasticGimnastic |
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| 27 Mar 22 | r29 | AlcoyanoAlcoyano | 0 - 0 | Villarreal BVillarreal B |
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| 02 Apr 22 | r30 | Villarreal BVillarreal B | 3 - 0 | Algeciras CFAlgeciras CF |
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| 09 Apr 22 | r31 | Barcelona BBarcelona B | 2 - 1 | Villarreal BVillarreal B |
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| 16 Apr 22 | r32 | Villarreal BVillarreal B | 5 - 0 | Linares DeportivoLinares Depor |
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| 23 Apr 22 | r33 | CornellàCornellà | 0 - 0 | Villarreal BVillarreal B |
| |
| 01 May 22 | r34 | Villarreal BVillarreal B | 2 - 1 | Atlético BalearesAtlético Bale |
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| 08 May 22 | r35 | Villarreal BVillarreal B | 4 - 1 | Real Madrid BReal Madrid B |
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| 14 May 22 | r36 | CastellónCastellón | 3 - 3 | Villarreal BVillarreal B |
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| 21 May 22 | r37 | Villarreal BVillarreal B | 0 - 0 | LinenseLinense |
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| 28 May 22 | r38 | Atlético SanluqueñoAtlético Sanl | 2 - 1 | Villarreal BVillarreal B |
Team 2021-2022 Schedules
Águilas
Alcorcón
Algeciras
Antequera
Atlético Madrileño
Cartagena
CE Europa
Gimnàstic
Hércules
Huesca
Ibiza
Juventud Torremolinos
Rayo Majadahonda
Real Jaén
Real Madrid Castilla
Real Murcia
Real Zaragoza
Sant Andreu
Teruel
Villarreal B
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