| 21 Nov 20 | r36  | FC AndorraFC Andorra | 1 - 0 | OlotOlot |
| 21 Nov 20 | r36 | Lleida EsportiuLleida Esport | 2 - 3 | CornellàCornellà |
| 22 Nov 20 | r36 | AE PratAE Prat | 0 - 1 | CF BadalonaCF Badalona |
| 22 Nov 20 | r36 | LlagosteraLlagostera | 2 - 0 | Espanyol BEspanyol B |
| 22 Nov 20 | r36 | L-'HospitaletL-'Hospitalet | 2 - 0 | Barcelona BBarcelona B |
| 29 Nov 20 | r36 | OrihuelaOrihuela | 1 - 0 | Peña DeportivaPeña Deportiv |
| 29 Nov 20 | r36 | Villarreal BVillarreal B | 1 - 1 | Valencia MestallaValencia Mest |
| 29 Nov 20 | r36 | UD IbizaUD Ibiza | 1 - 0 | HerculesHercules |
| 29 Nov 20 | r36 | Atlético LevanteAtlético Leva | 3 - 1 | AtzenetaAtzeneta |
| 29 Nov 20 | r36 | La NucíaLa Nucía | 0 - 0 | AlcoyanoAlcoyano |
| 08 May 21 | r36 | CF BadalonaCF Badalona | 1 - 1 | HerculesHercules |
| 09 May 21 | r36 | Espanyol BEspanyol B | 2 - 1 | OrihuelaOrihuela |
| 09 May 21 | r36 | AlcoyanoAlcoyano | 2 - 3 | FC AndorraFC Andorra |
| 09 May 21 | r36 | UD IbizaUD Ibiza | 4 - 0 | GimnasticGimnastic |
| 09 May 21 | r36 | Villarreal BVillarreal B | 3 - 4 | Barcelona BBarcelona B |
| 09 May 21 | r36 | CornellàCornellà | 2 - 1 | La NucíaLa Nucía |
| 09 May 21 | r36 | L-'HospitaletL-'Hospitalet | 0 - 1 | Peña DeportivaPeña Deportiv |
| 09 May 21 | r36 | AE PratAE Prat | 2 - 2 | AtzenetaAtzeneta |
| 09 May 21 | r36 | LlagosteraLlagostera | 2 - 0 | Atlético LevanteAtlético Leva |
| 09 May 21 | r36 | OlotOlot | 1 - 0 | Valencia MestallaValencia Mest |
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