| 07 Nov 20 | r34  | Atlético LevanteAtlético Leva | 0 - 1 | La NucíaLa Nucía |
| 07 Nov 20 | r34 | L-'HospitaletL-'Hospitalet | 2 - 1 | Espanyol BEspanyol B |
| 07 Nov 20 | r34 | FC AndorraFC Andorra | 1 - 0 | Barcelona BBarcelona B |
| 08 Nov 20 | r34 | OlotOlot | 1 - 1 | CF BadalonaCF Badalona |
| 08 Nov 20 | r34 | AE PratAE Prat | 1 - 1 | GimnasticGimnastic |
| 08 Nov 20 | r34 | HerculesHercules | 1 - 0 | Peña DeportivaPeña Deportiv |
| 08 Nov 20 | r34 | UD IbizaUD Ibiza | 1 - 0 | AtzenetaAtzeneta |
| 08 Nov 20 | r34 | OrihuelaOrihuela | 2 - 1 | Valencia MestallaValencia Mest |
| 25 Nov 20 | r34 | Villarreal BVillarreal B | 3 - 0 | AlcoyanoAlcoyano |
| 25 Nov 20 | r34 | Lleida EsportiuLleida Esport | 1 - 0 | LlagosteraLlagostera |
| 24 Apr 21 | r34 | AtzenetaAtzeneta | 2 - 0 | Espanyol BEspanyol B |
| 24 Apr 21 | r34 | La NucíaLa Nucía | 1 - 0 | Lleida EsportiuLleida Esport |
| 25 Apr 21 | r34 | Villarreal BVillarreal B | 1 - 2 | GimnasticGimnastic |
| 25 Apr 21 | r34 | UD IbizaUD Ibiza | 2 - 1 | FC AndorraFC Andorra |
| 25 Apr 21 | r34 | Atlético LevanteAtlético Leva | 1 - 1 | CF BadalonaCF Badalona |
| 25 Apr 21 | r34 | Peña DeportivaPeña Deportiv | 2 - 1 | OlotOlot |
| 25 Apr 21 | r34 | Valencia MestallaValencia Mest | 1 - 1 | L-'HospitaletL-'Hospitalet |
| 25 Apr 21 | r34 | AlcoyanoAlcoyano | 1 - 2 | Barcelona BBarcelona B |
| 25 Apr 21 | r34 | OrihuelaOrihuela | 0 - 0 | AE PratAE Prat |
| 05 May 21 | r34 | HerculesHercules | 2 - 0 | LlagosteraLlagostera |
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