| 31 Oct 20 | r33  | AtzenetaAtzeneta | 0 - 1 | OrihuelaOrihuela |
| 01 Nov 20 | r33 | GimnasticGimnastic | 2 - 0 | OlotOlot |
| 01 Nov 20 | r33 | CornellàCornellà | 2 - 2 | FC AndorraFC Andorra |
| 01 Nov 20 | r33 | Valencia MestallaValencia Mest | 0 - 0 | HerculesHercules |
| 01 Nov 20 | r33 | Peña DeportivaPeña Deportiv | 0 - 0 | Atlético LevanteAtlético Leva |
| 01 Nov 20 | r33 | CF BadalonaCF Badalona | 0 - 2 | Lleida EsportiuLleida Esport |
| 01 Nov 20 | r33 | La NucíaLa Nucía | 1 - 2 | Villarreal BVillarreal B |
| 01 Nov 20 | r33 | Barcelona BBarcelona B | 0 - 0 | AE PratAE Prat |
| 11 Nov 20 | r33 | LlagosteraLlagostera | 1 - 1 | L-'HospitaletL-'Hospitalet |
| 18 Nov 20 | r33 | AlcoyanoAlcoyano | 1 - 2 | UD IbizaUD Ibiza |
| 17 Apr 21 | r33 | L-'HospitaletL-'Hospitalet | 0 - 1 | AtzenetaAtzeneta |
| 18 Apr 21 | r33 | Lleida EsportiuLleida Esport | 0 - 0 | Atlético LevanteAtlético Leva |
| 18 Apr 21 | r33 | GimnasticGimnastic | 0 - 1 | UD IbizaUD Ibiza |
| 18 Apr 21 | r33 | AE PratAE Prat | 1 - 0 | Valencia MestallaValencia Mest |
| 18 Apr 21 | r33 | OlotOlot | 1 - 3 | OrihuelaOrihuela |
| 18 Apr 21 | r33 | FC AndorraFC Andorra | 0 - 0 | AlcoyanoAlcoyano |
| 18 Apr 21 | r33 | Barcelona BBarcelona B | 3 - 2 | Villarreal BVillarreal B |
| 18 Apr 21 | r33 | CornellàCornellà | 1 - 2 | HerculesHercules |
| 28 Apr 21 | r33 | LlagosteraLlagostera | 1 - 0 | La NucíaLa Nucía |
| 12 May 21 | r33 | Espanyol BEspanyol B | 0 - 0 | Peña DeportivaPeña Deportiv |
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