| 24 Oct 20 | r32  | Villarreal BVillarreal B | 1 - 1 | Atlético LevanteAtlético Leva |
| 24 Oct 20 | r32 | FC AndorraFC Andorra | 2 - 2 | Espanyol BEspanyol B |
| 24 Oct 20 | r32 | L-'HospitaletL-'Hospitalet | 3 - 2 | Lleida EsportiuLleida Esport |
| 25 Oct 20 | r32 | AE PratAE Prat | 1 - 0 | CornellàCornellà |
| 25 Oct 20 | r32 | Valencia MestallaValencia Mest | 0 - 0 | Peña DeportivaPeña Deportiv |
| 25 Oct 20 | r32 | UD IbizaUD Ibiza | 3 - 0 | La NucíaLa Nucía |
| 25 Oct 20 | r32 | GimnasticGimnastic | 0 - 0 | CF BadalonaCF Badalona |
| 25 Oct 20 | r32 | HerculesHercules | 2 - 1 | AtzenetaAtzeneta |
| 25 Oct 20 | r32 | OrihuelaOrihuela | 0 - 0 | AlcoyanoAlcoyano |
| 25 Nov 20 | r32 | OlotOlot | 2 - 1 | Barcelona BBarcelona B |
| 10 Apr 21 | r32 | AtzenetaAtzeneta | 1 - 2 | AE PratAE Prat |
| 10 Apr 21 | r32 | HerculesHercules | 1 - 0 | CF BadalonaCF Badalona |
| 10 Apr 21 | r32 | Valencia MestallaValencia Mest | 0 - 1 | OlotOlot |
| 11 Apr 21 | r32 | Peña DeportivaPeña Deportiv | 2 - 0 | L-'HospitaletL-'Hospitalet |
| 11 Apr 21 | r32 | Atlético LevanteAtlético Leva | 2 - 1 | LlagosteraLlagostera |
| 11 Apr 21 | r32 | La NucíaLa Nucía | 0 - 0 | CornellàCornellà |
| 11 Apr 21 | r32 | AlcoyanoAlcoyano | 1 - 1 | GimnasticGimnastic |
| 11 Apr 21 | r32 | Villarreal BVillarreal B | 1 - 3 | FC AndorraFC Andorra |
| 11 Apr 21 | r32 | UD IbizaUD Ibiza | 2 - 1 | Barcelona BBarcelona B |
| 11 Apr 21 | r32 | OrihuelaOrihuela | 2 - 1 | Espanyol BEspanyol B |
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