| 06 May 25 | r04      | Nacional PotosíNacional Poto | 2 - 2 | Club GuaraníClub Guaraní |
| 06 May 25 | r04 | VitóriaVitória | 1 - 1 | Defensa y JusticiaDefensa y Jus |
| 06 May 25 | r04 | Sportivo LuqueñoSportivo Luqu | 0 - 1 | Godoy CruzGodoy Cruz |
| 07 May 25 | r04 | Boston RiverBoston River | 1 - 5 | IndependienteIndependiente |
| 07 May 25 | r04 | CorinthiansCorinthians | 1 - 1 | América de CaliAmérica de Ca |
| 07 May 25 | r04 | MelgarMelgar | 0 - 1 | LanúsLanús |
| 07 May 25 | r04 | Cerro LargoCerro Largo | 1 - 3 | Universidad Católica del Universidad C |
| 07 May 25 | r04 | UniónUnión | 1 - 2 | PalestinoPalestino |
| 07 May 25 | r04 | Academia Puerto CabelloAcademia Puer | 4 - 1 | Vasco da GamaVasco da Gama |
| 08 May 25 | r04 | Atlético GrauAtlético Grau | 0 - 0 | GrêmioGrêmio |
| 08 May 25 | r04 | Mushuc RunaMushuc Runa | 1 - 1 | CruzeiroCruzeiro |
| 08 May 25 | r04 | Once CaldasOnce Caldas | 1 - 0 | Unión EspañolaUnión Español |
| 08 May 25 | r04 | Racing MontevideoRacing Montev | 1 - 3 | HuracánHuracán |
| 08 May 25 | r04 | Deportes IquiqueDeportes Iqui | 3 - 2 | Atlético MineiroAtlético Mine |
| 09 May 25 | r04 | GV San JoséGV San José | 1 - 0 | FluminenseFluminense |
| 09 May 25 | r04 | CiencianoCienciano | 3 - 1 | CaracasCaracas |
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