| 31 Jul 21 | r01   | ArbroathArbroath | 0 - 1 | Inverness CInverness C |
| 31 Jul 21 | r01 | MortonMorton | 2 - 2 | DunfermlineDunfermline |
| 31 Jul 21 | r01 | PartickPartick | 3 - 2 | Queen of SouthQueen of Sout |
| 31 Jul 21 | r01 | Raith RvsRaith Rvs | 4 - 4 | HamiltonHamilton |
| 02 Aug 21 | r01  | KilmarnockKilmarnock | 2 - 0 | AyrAyr |
| |
| 07 Aug 21 | r02 | Inverness CInverness C | 1 - 0 | Raith RvsRaith Rvs |
| 07 Aug 21 | r02 | AyrAyr | 2 - 2 | ArbroathArbroath |
| 07 Aug 21 | r02 | DunfermlineDunfermline | 0 - 3 | PartickPartick |
| 07 Aug 21 | r02 | HamiltonHamilton | 0 - 1 | MortonMorton |
| 07 Aug 21 | r02 | Queen of SouthQueen of Sout | 0 - 1 | KilmarnockKilmarnock |
| |
| 21 Aug 21 | r03 | Inverness CInverness C | 1 - 0 | AyrAyr |
| 21 Aug 21 | r03 | ArbroathArbroath | 3 - 1 | PartickPartick |
| 21 Aug 21 | r03 | HamiltonHamilton | 0 - 2 | KilmarnockKilmarnock |
| 21 Aug 21 | r03 | MortonMorton | 2 - 3 | Queen of SouthQueen of Sout |
| |
| 28 Aug 21 | r04 | DunfermlineDunfermline | 0 - 3 | ArbroathArbroath |
| 28 Aug 21 | r04 | KilmarnockKilmarnock | 0 - 1 | Inverness CInverness C |
| 28 Aug 21 | r04 | PartickPartick | 3 - 0 | MortonMorton |
| 28 Aug 21 | r04 | Queen of SouthQueen of Sout | 1 - 2 | HamiltonHamilton |
| 07 Sep 21 | r04 | AyrAyr | 0 - 2 | Raith RvsRaith Rvs |
| |
| 11 Sep 21 | r05 | Inverness CInverness C | 3 - 1 | PartickPartick |
| 11 Sep 21 | r05 | ArbroathArbroath | 4 - 0 | HamiltonHamilton |
| 11 Sep 21 | r05 | AyrAyr | 3 - 1 | DunfermlineDunfermline |
| 11 Sep 21 | r05 | KilmarnockKilmarnock | 1 - 0 | MortonMorton |
| 11 Sep 21 | r05 | Raith RvsRaith Rvs | 0 - 1 | Queen of SouthQueen of Sout |
| |
| 18 Sep 21 | r06 | DunfermlineDunfermline | 0 - 0 | Inverness CInverness C |
| 18 Sep 21 | r06 | HamiltonHamilton | 0 - 2 | AyrAyr |
| 18 Sep 21 | r06 | MortonMorton | 0 - 1 | Raith RvsRaith Rvs |
| 18 Sep 21 | r06 | PartickPartick | 0 - 2 | KilmarnockKilmarnock |
| 18 Sep 21 | r06 | Queen of SouthQueen of Sout | 0 - 2 | ArbroathArbroath |
| |
| 24 Sep 21 | r07 | ArbroathArbroath | 0 - 0 | KilmarnockKilmarnock |
| 25 Sep 21 | r07 | Inverness CInverness C | 2 - 1 | Queen of SouthQueen of Sout |
| 25 Sep 21 | r07 | AyrAyr | 0 - 0 | MortonMorton |
| 25 Sep 21 | r07 | DunfermlineDunfermline | 0 - 0 | HamiltonHamilton |
| 26 Sep 21 | r07 | Raith RvsRaith Rvs | 3 - 2 | PartickPartick |
| |
| 29 Sep 21 | r03 | Raith RvsRaith Rvs | 1 - 1 | DunfermlineDunfermline |
| |
| 02 Oct 21 | r08 | HamiltonHamilton | 2 - 1 | Inverness CInverness C |
| 02 Oct 21 | r08 | KilmarnockKilmarnock | 1 - 3 | Raith RvsRaith Rvs |
| 02 Oct 21 | r08 | MortonMorton | 2 - 2 | ArbroathArbroath |
| 02 Oct 21 | r08 | PartickPartick | 4 - 0 | AyrAyr |
| 02 Oct 21 | r08 | Queen of SouthQueen of Sout | 1 - 0 | DunfermlineDunfermline |
| |
| 15 Oct 21 | r09 | HamiltonHamilton | 1 - 6 | PartickPartick |
| 16 Oct 21 | r09 | Inverness CInverness C | 2 - 0 | MortonMorton |
| 16 Oct 21 | r09 | AyrAyr | 2 - 1 | Queen of SouthQueen of Sout |
| 16 Oct 21 | r09 | DunfermlineDunfermline | 2 - 2 | KilmarnockKilmarnock |
| 16 Oct 21 | r09 | Raith RvsRaith Rvs | 2 - 1 | ArbroathArbroath |
| |
| 23 Oct 21 | r10 | ArbroathArbroath | 1 - 1 | AyrAyr |
| 23 Oct 21 | r10 | KilmarnockKilmarnock | 2 - 1 | HamiltonHamilton |
| 23 Oct 21 | r10 | PartickPartick | 0 - 0 | DunfermlineDunfermline |
| 23 Oct 21 | r10 | Queen of SouthQueen of Sout | 0 - 0 | MortonMorton |
| 23 Oct 21 | r10 | Raith RvsRaith Rvs | 1 - 1 | Inverness CInverness C |
| |
| 26 Oct 21 | r11 | Inverness CInverness C | 0 - 1 | ArbroathArbroath |
| 26 Oct 21 | r11 | MortonMorton | 0 - 0 | PartickPartick |
| 26 Oct 21 | r11 | AyrAyr | 0 - 1 | KilmarnockKilmarnock |
| 26 Oct 21 | r11 | DunfermlineDunfermline | 1 - 1 | Raith RvsRaith Rvs |
| 26 Oct 21 | r11 | HamiltonHamilton | 1 - 0 | Queen of SouthQueen of Sout |
| |
| 30 Oct 21 | r12 | ArbroathArbroath | 4 - 2 | DunfermlineDunfermline |
| 30 Oct 21 | r12 | KilmarnockKilmarnock | 4 - 0 | Queen of SouthQueen of Sout |
| 30 Oct 21 | r12 | MortonMorton | 1 - 1 | HamiltonHamilton |
| 30 Oct 21 | r12 | PartickPartick | 0 - 0 | Inverness CInverness C |
| 30 Oct 21 | r12 | Raith RvsRaith Rvs | 2 - 1 | AyrAyr |
| |
| 06 Nov 21 | r13 | AyrAyr | 2 - 2 | Inverness CInverness C |
| 06 Nov 21 | r13 | DunfermlineDunfermline | 1 - 3 | MortonMorton |
| 06 Nov 21 | r13 | HamiltonHamilton | 1 - 1 | ArbroathArbroath |
| 06 Nov 21 | r13 | KilmarnockKilmarnock | 0 - 1 | PartickPartick |
| 06 Nov 21 | r13 | Queen of SouthQueen of Sout | 1 - 1 | Raith RvsRaith Rvs |
| |
| 13 Nov 21 | r14 | ArbroathArbroath | 1 - 1 | Queen of SouthQueen of Sout |
| 13 Nov 21 | r14 | AyrAyr | 0 - 4 | PartickPartick |
| 13 Nov 21 | r14 | HamiltonHamilton | 0 - 3 | Raith RvsRaith Rvs |
| 13 Nov 21 | r14 | Inverness CInverness C | 1 - 2 | DunfermlineDunfermline |
| 13 Nov 21 | r14 | MortonMorton | 0 - 2 | KilmarnockKilmarnock |
| |
| 19 Nov 21 | r15 | Queen of SouthQueen of Sout | 1 - 2 | Inverness CInverness C |
| 20 Nov 21 | r15 | DunfermlineDunfermline | 3 - 0 | AyrAyr |
| 20 Nov 21 | r15 | KilmarnockKilmarnock | 0 - 1 | ArbroathArbroath |
| 20 Nov 21 | r15 | PartickPartick | 1 - 0 | HamiltonHamilton |
| 20 Nov 21 | r15 | Raith RvsRaith Rvs | 2 - 1 | MortonMorton |
| |
| 03 Dec 21 | r16 | Inverness CInverness C | 1 - 0 | KilmarnockKilmarnock |
| 04 Dec 21 | r16 | ArbroathArbroath | 0 - 0 | Raith RvsRaith Rvs |
| 04 Dec 21 | r16 | HamiltonHamilton | 1 - 0 | DunfermlineDunfermline |
| 04 Dec 21 | r16 | MortonMorton | 2 - 2 | AyrAyr |
| 04 Dec 21 | r16 | Queen of SouthQueen of Sout | 0 - 0 | PartickPartick |
| |
| 10 Dec 21 | r17 | AyrAyr | 1 - 1 | HamiltonHamilton |
| 11 Dec 21 | r17 | DunfermlineDunfermline | 3 - 3 | Queen of SouthQueen of Sout |
| 11 Dec 21 | r17 | MortonMorton | 1 - 6 | Inverness CInverness C |
| 11 Dec 21 | r17 | PartickPartick | 0 - 2 | ArbroathArbroath |
| 11 Dec 21 | r17 | Raith RvsRaith Rvs | 1 - 0 | KilmarnockKilmarnock |
| |
| 18 Dec 21 | r18 | ArbroathArbroath | 2 - 1 | MortonMorton |
| 18 Dec 21 | r18 | Inverness CInverness C | 1 - 2 | HamiltonHamilton |
| 18 Dec 21 | r18 | PartickPartick | 1 - 0 | Raith RvsRaith Rvs |
| 18 Dec 21 | r18 | Queen of SouthQueen of Sout | 3 - 0 | AyrAyr |
| |
| 26 Dec 21 | r19 | AyrAyr | 2 - 0 | Raith RvsRaith Rvs |
| 26 Dec 21 | r19 | DunfermlineDunfermline | 0 - 3 | ArbroathArbroath |
| 26 Dec 21 | r19 | HamiltonHamilton | 2 - 3 | KilmarnockKilmarnock |
| |
| 29 Dec 21 | r20 | KilmarnockKilmarnock | 1 - 1 | MortonMorton |
| |
| 02 Jan 22 | r21 | ArbroathArbroath | 0 - 0 | Inverness CInverness C |
| 02 Jan 22 | r21 | Queen of SouthQueen of Sout | 0 - 3 | HamiltonHamilton |
| 02 Jan 22 | r21 | Raith RvsRaith Rvs | 0 - 0 | DunfermlineDunfermline |
| |
| 08 Jan 22 | r22 | AyrAyr | 1 - 0 | ArbroathArbroath |
| 08 Jan 22 | r22 | HamiltonHamilton | 2 - 2 | PartickPartick |
| 08 Jan 22 | r22 | Inverness CInverness C | 1 - 1 | Raith RvsRaith Rvs |
| 08 Jan 22 | r22 | MortonMorton | 5 - 0 | DunfermlineDunfermline |
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