| 27 Oct 22 | r05    | FiorentinaFiorentina | 2 - 1 | Istanbul BasaksehirIstanbul Basa |
| 27 Oct 22 | r05 | AnderlechtAnderlecht | 2 - 2 | Steaua BucurestiSteaua Bucure |
| 27 Oct 22 | r05 | VillarrealVillarreal | 2 - 2 | Hapoel Beer ShevaHapoel Beer S |
| 27 Oct 22 | r05 | Austria ViennaAustria Vienn | 1 - 1 | Lech PoznanLech Poznan |
| 27 Oct 22 | r05 | NiceNice | 2 - 1 | Partizan BelgradePartizan Belg |
| 27 Oct 22 | r05 | VaduzVaduz | 1 - 2 | AZ AlkmaarAZ Alkmaar |
| 27 Oct 22 | r05 | Slovan BratislavaSlovan Bratis | 2 - 1 | Pyunik YerevanPyunik Yereva |
| 27 Oct 22 | r05 | HeartsHearts | 2 - 1 | Rīgas Futbola SkolaRīgas Futbola |
| 27 Oct 22 | r05 | West HamWest Ham | 1 - 0 | Silkeborg IFSilkeborg IF |
| 27 Oct 22 | r05 | SC Dnipro-1SC Dnipro-1 | 1 - 0 | Apollon LimassolApollon Limas |
| 27 Oct 22 | r05 | MoldeMolde | 2 - 3 | DjurgaardenDjurgaarden |
| 27 Oct 22 | r05 | ShamrockShamrock | 1 - 1 | GentGent |
| 27 Oct 22 | r05 | BallkaniBallkani | 0 - 1 | Slavia PragueSlavia Prague |
| 27 Oct 22 | r05 | SivassporSivasspor | 3 - 0 | CFR Cluj-NapocaCFR Cluj-Napo |
| 27 Oct 22 | r05 | FC BaselFC Basel | 2 - 2 | VMFD ZalgirisVMFD Zalgiris |
| 28 Oct 22 | r05 | SlovackoSlovacko | 0 - 0 | FC KolnFC Koln |
| 28 Oct 22 | r05 | SlovackoSlovacko | 0 - 1 | FC KolnFC Koln |
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