| 09 May 16 | r25  |  Internazionali BNL dItalia Makarova vs Kovinic |
| 09 May 16 | r25 | Internazionali BNL dItalia Schmiedlova vs Friedsam |
| 09 May 16 | r25 | Internazionali BNL dItalia Beck vs Pereira |
| 09 May 16 | r25 | Internazionali BNL dItalia Williams vs Vandeweghe |
| 09 May 16 | r25 | Internazionali BNL dItalia Doi vs Cornet |
| 09 May 16 | r25 | Internazionali BNL dItalia Pliskova K vs Kasatkina |
| 09 May 16 | r25 | Internazionali BNL dItalia Strycova vs Knapp |
| 09 May 16 | r25 | Internazionali BNL dItalia Errani vs Watson |
| 09 May 16 | r25 | Internazionali BNL dItalia Safarova vs Schiavone |
| 09 May 16 | r25 | Internazionali BNL dItalia Begu vs Gasparyan |
| 09 May 16 | r25 | Internazionali BNL dItalia Svitolina vs Puig |
| 09 May 16 | r25 | Internazionali BNL dItalia Keys vs Petkovic |
| 09 May 16 | r25 | Internazionali BNL dItalia Ivanovic vs Pavlyuchenkova |
| 10 May 16 | r25 | Internazionali BNL dItalia Babos vs Bertens |
| 10 May 16 | r25 | Internazionali BNL dItalia Kuznetsova vs Garcia |
| 10 May 16 | r25 | Internazionali BNL dItalia Mladenovic vs Ostapenko |
| 10 May 16 | r25 | Internazionali BNL dItalia Niculescu vs Duque Marino |
| 10 May 16 | r25 | Internazionali BNL dItalia Jankovic vs Bouchard |
| 10 May 16 | r25 | Internazionali BNL dItalia Konta vs Larsson |
| 10 May 16 | r25 | Internazionali BNL dItalia Stosur vs Riske |
| 10 May 16 | r25 | Internazionali BNL dItalia Mchale vs Giovine |
| 10 May 16 | r25 | Internazionali BNL dItalia Tsurenko vs Goerges |
| 10 May 16 | r25 | Internazionali BNL dItalia Gavrilova vs Lisicki |
| 10 May 16 | r25 | Internazionali BNL dItalia Bacsinszky vs Wickmayer |
| 10 May 16 | r25 | Internazionali BNL dItalia Suarez Navarro vs Pereira |
| 10 May 16 | r25 | Internazionali BNL dItalia Williams vs Friedsam |
| 11 May 16 | r25 | Internazionali BNL dItalia Azarenka vs Begu |
| 11 May 16 | r25 | Internazionali BNL dItalia Kasatkina vs Duque Marino |
| 11 May 16 | r25 | Internazionali BNL dItalia Muguruza vs Makarova |
| 11 May 16 | r25 | Internazionali BNL dItalia Ostapenko vs Puig |
| 11 May 16 | r25 | Internazionali BNL dItalia Strycova vs Watson |
| 11 May 16 | r25 | Internazionali BNL dItalia Kerber vs Bouchard |
| 11 May 16 | r25 | Internazionali BNL dItalia Bacsinszky vs Tsurenko |
| 11 May 16 | r25 | Internazionali BNL dItalia Ivanovic vs Mchale |
| 11 May 16 | r25 | Internazionali BNL dItalia Kuznetsova vs Stosur |
| 11 May 16 | r25 | Internazionali BNL dItalia Halep vs Gavrilova |
| 11 May 16 | r25 | Internazionali BNL dItalia Vinci vs Konta |
| 11 May 16 | r25 | Internazionali BNL dItalia Safarova vs Doi |
| 11 May 16 | r25 | Internazionali BNL dItalia Williams vs Babos |
| 11 May 16 | r25 | Internazionali BNL dItalia Kvitova vs Keys |
| 12 May 16 | r25 | Internazionali BNL dItalia Muguruza vs Ostapenko |
| 12 May 16 | r25 | Internazionali BNL dItalia Kasatkina vs Begu |
| 12 May 16 | r25 | Internazionali BNL dItalia Bacsinszky vs Suarez Navarro |
| 12 May 16 | r25 | Internazionali BNL dItalia Kuznetsova vs Gavrilova |
| 12 May 16 | r25 | Internazionali BNL dItalia Williams vs Mchale |
| 12 May 16 | r25 | Internazionali BNL dItalia Konta vs Doi |
| 12 May 16 | r25 | Internazionali BNL dItalia Keys vs Babos |
| 12 May 16 | r25 | Internazionali BNL dItalia Strycova vs Bouchard |
| 13 May 16 | r25 | Internazionali BNL dItalia Muguruza vs Bacsinszky |
| 13 May 16 | r25 | Internazionali BNL dItalia Begu vs Doi |
| 13 May 16 | r25 | Internazionali BNL dItalia Keys vs Strycova |
| 13 May 16 | r25 | Internazionali BNL dItalia Williams vs Kuznetsova |
| 14 May 16 | r25 | Internazionali BNL dItalia Muguruza vs Keys |
| 14 May 16 | r25 | Internazionali BNL dItalia Williams vs Begu |
| 15 May 16 | r25 | Internazionali BNL dItalia Williams vs Keys |
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