| 30 Apr 16 | r24  |  Mutua Madrid Open Makarova vs Beck |
| 30 Apr 16 | r24 | Mutua Madrid Open Svitolina vs Wickmayer |
| 30 Apr 16 | r24 | Mutua Madrid Open Errani vs Giorgi |
| 30 Apr 16 | r24 | Mutua Madrid Open Friedsam vs Mchale |
| 30 Apr 16 | r24 | Mutua Madrid Open Cornet vs Badosa Gibert |
| 30 Apr 16 | r24 | Mutua Madrid Open Stephens vs Pereira |
| 01 May 16 | r24 | Mutua Madrid Open Gavrilova vs Watson |
| 01 May 16 | r24 | Mutua Madrid Open Vinci vs Kovinic |
| 01 May 16 | r24 | Mutua Madrid Open Pliskova K vs Dominguez Lino |
| 01 May 16 | r24 | Mutua Madrid Open Pavlyuchenkova vs Tsurenko |
| 01 May 16 | r24 | Mutua Madrid Open Keys vs Riske |
| 01 May 16 | r24 | Mutua Madrid Open Suarez Navarro vs Babos |
| 01 May 16 | r24 | Mutua Madrid Open Kasatkina vs Tig |
| 01 May 16 | r24 | Mutua Madrid Open Kerber vs Strycova |
| 01 May 16 | r24 | Mutua Madrid Open Ostapenko vs Vesnina |
| 01 May 16 | r24 | Mutua Madrid Open Muguruza vs Schmiedlova |
| 01 May 16 | r24 | Mutua Madrid Open Lisicki vs Puig |
| 01 May 16 | r24 | Mutua Madrid Open Niculescu vs Chirico |
| 01 May 16 | r24 | Mutua Madrid Open Kvitova vs Arruabarrena |
| 01 May 16 | r24 | Mutua Madrid Open Jankovic vs Cirstea |
| 01 May 16 | r24 | Mutua Madrid Open Safarova vs Vandeweghe |
| 01 May 16 | r24 | Mutua Madrid Open Ivanovic vs Siniakova |
| 01 May 16 | r24 | Mutua Madrid Open Konta vs Garcia |
| 01 May 16 | r24 | Mutua Madrid Open Azarenka vs Robson |
| 01 May 16 | r24 | Mutua Madrid Open Kuznetsova vs Siegemund |
| 01 May 16 | r24 | Mutua Madrid Open Mladenovic vs Lucic Baroni |
| 01 May 16 | r24 | Mutua Madrid Open Stosur vs Sorribes Tormo |
| 01 May 16 | r24 | Mutua Madrid Open Bacsinszky vs Petkovic |
| 01 May 16 | r24 | Mutua Madrid Open Halep vs Doi |
| 01 May 16 | r24 | Mutua Madrid Open Begu vs Bouchard |
| 01 May 16 | r24 | Mutua Madrid Open Gasparyan vs Knapp |
| 01 May 16 | r24 | Mutua Madrid Open Radwanska vs Cibulkova |
| 02 May 16 | r24 | Mutua Madrid Open Pliskova K vs Mchale |
| 02 May 16 | r24 | Mutua Madrid Open Stephens vs Tig |
| 02 May 16 | r24 | Mutua Madrid Open Svitolina vs Gavrilova |
| 02 May 16 | r24 | Mutua Madrid Open Kvitova vs Vesnina |
| 02 May 16 | r24 | Mutua Madrid Open Azarenka vs Cornet |
| 02 May 16 | r24 | Mutua Madrid Open Keys vs Strycova |
| 02 May 16 | r24 | Mutua Madrid Open Ivanovic vs Chirico |
| 02 May 16 | r24 | Mutua Madrid Open Muguruza vs Begu |
| 03 May 16 | r24 | Mutua Madrid Open Safarova vs Stosur |
| 03 May 16 | r24 | Mutua Madrid Open Halep vs Knapp |
| 03 May 16 | r24 | Mutua Madrid Open Bacsinszky vs Makarova |
| 03 May 16 | r24 | Mutua Madrid Open Pavlyuchenkova vs Giorgi |
| 03 May 16 | r24 | Mutua Madrid Open Suarez Navarro vs Lisicki |
| 03 May 16 | r24 | Mutua Madrid Open Cibulkova vs Garcia |
| 03 May 16 | r24 | Mutua Madrid Open Siegemund vs Lucic Baroni |
| 03 May 16 | r24 | Mutua Madrid Open Kovinic vs Cirstea |
| 04 May 16 | r24 | Mutua Madrid Open Kvitova vs Gavrilova |
| 04 May 16 | r24 | Mutua Madrid Open Begu vs Mchale |
| 04 May 16 | r24 | Mutua Madrid Open Halep vs Bacsinszky |
| 04 May 16 | r24 | Mutua Madrid Open Azarenka vs Chirico |
| 04 May 16 | r24 | Mutua Madrid Open Siegemund vs Cirstea |
| 04 May 16 | r24 | Mutua Madrid Open Pavlyuchenkova vs Cibulkova |
| 04 May 16 | r24 | Mutua Madrid Open Suarez Navarro vs Stosur |
| 04 May 16 | r24 | Mutua Madrid Open Keys vs Tig |
| 05 May 16 | r24 | Mutua Madrid Open Gavrilova vs Chirico |
| 05 May 16 | r24 | Mutua Madrid Open Halep vs Begu |
| 05 May 16 | r24 | Mutua Madrid Open Cibulkova vs Cirstea |
| 05 May 16 | r24 | Mutua Madrid Open Stosur vs Tig |
| 06 May 16 | r24 | Mutua Madrid Open Cibulkova vs Chirico |
| 06 May 16 | r24 | Mutua Madrid Open Halep vs Stosur |
| 07 May 16 | r24 | Mutua Madrid Open Halep vs Cibulkova |
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