| 15 Feb 16 | r10  |  Rio Open Bogdan vs Ce |
| 15 Feb 16 | r10 | Rio Open Tatishvili vs Cepede Royg |
| 15 Feb 16 | r10 | Rio Open Hercog vs Brady |
| 15 Feb 16 | r10 | Rio Open Mitu vs Rogers |
| 15 Feb 16 | r10 | Rio Open Kovinic vs Vickery |
| 15 Feb 16 | r10 | Rio Open Cirstea vs Haddad Maia |
| 15 Feb 16 | r10 | Rio Open Duque Marino vs Parmentier |
| 15 Feb 16 | r10 | Rio Open Maria vs Schiavone |
| 15 Feb 16 | r10 | Rio Open Mchale vs Burger |
| 15 Feb 16 | r10 | Rio Open Irigoyen vs Kostova |
| 16 Feb 16 | r10 | Rio Open Glushko vs Goncalves |
| 16 Feb 16 | r10 | Rio Open Oprandi vs Soler Espinosa |
| 16 Feb 16 | r10 | Rio Open Arruabarrena vs Peterson |
| 16 Feb 16 | r10 | Rio Open Larsson vs Dominguez Lino |
| 16 Feb 16 | r10 | Rio Open Pereira vs Martic |
| 16 Feb 16 | r10 | Rio Open Torro Flor vs Erakovic |
| 17 Feb 16 | r10 | Rio Open Duque Marino vs Schiavone |
| 17 Feb 16 | r10 | Rio Open Hercog vs Cirstea |
| 17 Feb 16 | r10 | Rio Open Burger vs Kostova |
| 17 Feb 16 | r10 | Rio Open Cepede Royg vs Rogers |
| 18 Feb 16 | r10 | Rio Open Arruabarrena vs Bogdan |
| 18 Feb 16 | r10 | Rio Open Larsson vs Goncalves |
| 18 Feb 16 | r10 | Rio Open Kovinic vs Soler Espinosa |
| 18 Feb 16 | r10 | Rio Open Martic vs Erakovic |
| 19 Feb 16 | r10 | Rio Open Schiavone vs Burger |
| 19 Feb 16 | r10 | Rio Open Arruabarrena vs Martic |
| 19 Feb 16 | r10 | Rio Open Rogers vs Goncalves |
| 19 Feb 16 | r10 | Rio Open Kovinic vs Cirstea |
| 20 Feb 16 | r10 | Rio Open Schiavone vs Martic |
| 20 Feb 16 | r10 | Rio Open Rogers vs Cirstea |
| 21 Feb 16 | r10 | Rio Open Rogers vs Schiavone |
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