| 17 Feb 14 | r11  |  Rio Open Soler Espinosa vs Pigossi |
| 17 Feb 14 | r11 | Rio Open Larsson vs Van Uytvanck |
| 17 Feb 14 | r11 | Rio Open Torro Flor vs Burnett |
| 17 Feb 14 | r11 | Rio Open Bertens vs Kovinic |
| 17 Feb 14 | r11 | Rio Open Piter vs Haddad Maia |
| 17 Feb 14 | r11 | Rio Open Ormaechea vs Gibbs |
| 18 Feb 14 | r11 | Rio Open Scheepers vs Babos |
| 18 Feb 14 | r11 | Rio Open Zahlavova Strycova vs Pfizenmaier |
| 18 Feb 14 | r11 | Rio Open Zakopalova vs Duque Marino |
| 18 Feb 14 | r11 | Rio Open Schiavone vs Dominguez Lino |
| 18 Feb 14 | r11 | Rio Open King vs Begu |
| 18 Feb 14 | r11 | Rio Open Cadantu vs Pereira |
| 18 Feb 14 | r11 | Rio Open Cepede Royg vs Goncalves |
| 18 Feb 14 | r11 | Rio Open Shvedova vs Mayr |
| 19 Feb 14 | r11 | Rio Open Kichenok vs Friedsam |
| 19 Feb 14 | r11 | Rio Open Nara vs Hsieh |
| 19 Feb 14 | r11 | Rio Open Ormaechea vs Bertens |
| 19 Feb 14 | r11 | Rio Open Pfizenmaier vs Piter |
| 19 Feb 14 | r11 | Rio Open Van Uytvanck vs Burnett |
| 19 Feb 14 | r11 | Rio Open Zakopalova vs Soler Espinosa |
| 20 Feb 14 | r11 | Rio Open Nara vs Friedsam |
| 20 Feb 14 | r11 | Rio Open Dominguez Lino vs Scheepers |
| 20 Feb 14 | r11 | Rio Open Begu vs Cepede Royg |
| 20 Feb 14 | r11 | Rio Open Mayr vs Pereira |
| 21 Feb 14 | r11 | Rio Open Nara vs Dominguez Lino |
| 21 Feb 14 | r11 | Rio Open Pereira vs Begu |
| 21 Feb 14 | r11 | Rio Open Zakopalova vs Piter |
| 21 Feb 14 | r11 | Rio Open Ormaechea vs Burnett |
| 22 Feb 14 | r11 | Rio Open Nara vs Burnett |
| 22 Feb 14 | r11 | Rio Open Zakopalova vs Pereira |
| 23 Feb 14 | r11 | Rio Open Zakopalova vs Nara |
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