| 04 May 13 | r24  |  Mutua Madrid Open Goerges vs Jovanovski |
| 04 May 13 | r24 | Mutua Madrid Open Cornet vs Bertens |
| 04 May 13 | r24 | Mutua Madrid Open Lisicki vs Arvidsson |
| 04 May 13 | r24 | Mutua Madrid Open Stephens vs Hantuchova |
| 04 May 13 | r24 | Mutua Madrid Open Flipkens vs Barthel |
| 04 May 13 | r24 | Mutua Madrid Open Robson vs Rybarikova |
| 04 May 13 | r24 | Mutua Madrid Open Errani vs Radwanska |
| 04 May 13 | r24 | Mutua Madrid Open Dominguez Lino vs Halep |
| 05 May 13 | r24 | Mutua Madrid Open Wozniacki vs Shvedova |
| 05 May 13 | r24 | Mutua Madrid Open Bartoli vs Vesnina |
| 05 May 13 | r24 | Mutua Madrid Open Voegele vs Medina Garrigues |
| 05 May 13 | r24 | Mutua Madrid Open Cibulkova vs Tsurenko |
| 05 May 13 | r24 | Mutua Madrid Open Kerber vs Hsieh |
| 05 May 13 | r24 | Mutua Madrid Open Kanepi vs Pennetta |
| 05 May 13 | r24 | Mutua Madrid Open Radwanska vs Pironkova |
| 05 May 13 | r24 | Mutua Madrid Open Williams vs Putintseva |
| 05 May 13 | r24 | Mutua Madrid Open Schiavone vs Torro Flor |
| 05 May 13 | r24 | Mutua Madrid Open Kvitova vs Wickmayer |
| 05 May 13 | r24 | Mutua Madrid Open Cirstea vs Morita |
| 05 May 13 | r24 | Mutua Madrid Open Ivanovic vs Mattek Sands |
| 05 May 13 | r24 | Mutua Madrid Open Jankovic vs Scheepers |
| 05 May 13 | r24 | Mutua Madrid Open Li vs Keys |
| 05 May 13 | r24 | Mutua Madrid Open Petrova vs Giorgi |
| 05 May 13 | r24 | Mutua Madrid Open Makarova vs Safarova |
| 05 May 13 | r24 | Mutua Madrid Open Kirilenko vs Zakopalova |
| 05 May 13 | r24 | Mutua Madrid Open Kuznetsova vs Zheng |
| 05 May 13 | r24 | Mutua Madrid Open Vinci vs Lepchenko |
| 06 May 13 | r24 | Mutua Madrid Open Stosur vs Suarez Navarro |
| 06 May 13 | r24 | Mutua Madrid Open Mladenovic vs Soler Espinosa |
| 06 May 13 | r24 | Mutua Madrid Open Peng vs Mchale |
| 06 May 13 | r24 | Mutua Madrid Open Sharapova vs Dulgheru |
| 06 May 13 | r24 | Mutua Madrid Open Azarenka vs Pavlyuchenkova |
| 06 May 13 | r24 | Mutua Madrid Open Kerber vs Cornet |
| 06 May 13 | r24 | Mutua Madrid Open Errani vs Cirstea |
| 06 May 13 | r24 | Mutua Madrid Open Radwanska vs Robson |
| 07 May 13 | r24 | Mutua Madrid Open Bartoli vs Torro Flor |
| 07 May 13 | r24 | Mutua Madrid Open Flipkens vs Shvedova |
| 07 May 13 | r24 | Mutua Madrid Open Williams vs Dominguez Lino |
| 07 May 13 | r24 | Mutua Madrid Open Cibulkova vs Lisicki |
| 07 May 13 | r24 | Mutua Madrid Open Keys vs Medina Garrigues |
| 07 May 13 | r24 | Mutua Madrid Open Petrova vs Kuznetsova |
| 07 May 13 | r24 | Mutua Madrid Open Ivanovic vs Scheepers |
| 07 May 13 | r24 | Mutua Madrid Open Sharapova vs Mchale |
| 08 May 13 | r24 | Mutua Madrid Open Lepchenko vs Goerges |
| 08 May 13 | r24 | Mutua Madrid Open Suarez Navarro vs Kanepi |
| 08 May 13 | r24 | Mutua Madrid Open Azarenka vs Makarova |
| 08 May 13 | r24 | Mutua Madrid Open Kirilenko vs Mladenovic |
| 08 May 13 | r24 | Mutua Madrid Open Kvitova vs Hantuchova |
| 08 May 13 | r24 | Mutua Madrid Open Kerber vs Kuznetsova |
| 08 May 13 | r24 | Mutua Madrid Open Ivanovic vs Robson |
| 09 May 13 | r24 | Mutua Madrid Open Sharapova vs Lisicki |
| 09 May 13 | r24 | Mutua Madrid Open Shvedova vs Medina Garrigues |
| 09 May 13 | r24 | Mutua Madrid Open Williams vs Kirilenko |
| 09 May 13 | r24 | Mutua Madrid Open Kanepi vs Hantuchova |
| 09 May 13 | r24 | Mutua Madrid Open Bartoli vs Makarova |
| 09 May 13 | r24 | Mutua Madrid Open Errani vs Lepchenko |
| 10 May 13 | r24 | Mutua Madrid Open Williams vs Medina Garrigues |
| 10 May 13 | r24 | Mutua Madrid Open Sharapova vs Kanepi |
| 10 May 13 | r24 | Mutua Madrid Open Errani vs Makarova |
| 10 May 13 | r24 | Mutua Madrid Open Kerber vs Ivanovic |
| 11 May 13 | r24 | Mutua Madrid Open Williams vs Errani |
| 11 May 13 | r24 | Mutua Madrid Open Sharapova vs Ivanovic |
| 12 May 13 | r24 | Mutua Madrid Open Williams vs Sharapova |
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