| 05 May 12 | r24  |  Mutua Madrid Open Bartoli vs Cirstea |
| 05 May 12 | r24 | Mutua Madrid Open Paszek vs Soler Espinosa |
| 05 May 12 | r24 | Mutua Madrid Open Stosur vs Martic |
| 05 May 12 | r24 | Mutua Madrid Open Mchale vs Arvidsson |
| 05 May 12 | r24 | Mutua Madrid Open Zvonareva vs Cetkovska |
| 05 May 12 | r24 | Mutua Madrid Open Halep vs Williams |
| 05 May 12 | r24 | Mutua Madrid Open Zakopalova vs Benesova |
| 05 May 12 | r24 | Mutua Madrid Open Goerges vs Barthel |
| 05 May 12 | r24 | Mutua Madrid Open Li vs Muguruza Blanco |
| 06 May 12 | r24 | Mutua Madrid Open Wozniacki vs Pervak |
| 06 May 12 | r24 | Mutua Madrid Open Petrova vs King |
| 06 May 12 | r24 | Mutua Madrid Open Wickmayer vs Gajdosova |
| 06 May 12 | r24 | Mutua Madrid Open Niculescu vs Dominguez Lino |
| 06 May 12 | r24 | Mutua Madrid Open Hercog vs Peer |
| 06 May 12 | r24 | Mutua Madrid Open Radwanska vs Arruabarrena Vecino |
| 06 May 12 | r24 | Mutua Madrid Open Kerber vs Larsson |
| 06 May 12 | r24 | Mutua Madrid Open Ivanovic vs Johansson |
| 06 May 12 | r24 | Mutua Madrid Open Pavlyuchenkova vs Craybas |
| 06 May 12 | r24 | Mutua Madrid Open Medina Garrigues vs Pironkova |
| 06 May 12 | r24 | Mutua Madrid Open Schiavone vs Lepchenko |
| 06 May 12 | r24 | Mutua Madrid Open Azarenka vs Kuznetsova |
| 06 May 12 | r24 | Mutua Madrid Open Cibulkova vs Vinci |
| 06 May 12 | r24 | Mutua Madrid Open Kirilenko vs Zheng |
| 06 May 12 | r24 | Mutua Madrid Open Sharapova vs Begu |
| 07 May 12 | r24 | Mutua Madrid Open Peng vs Hradecka |
| 07 May 12 | r24 | Mutua Madrid Open Williams vs Vesnina |
| 07 May 12 | r24 | Mutua Madrid Open Rodionova A vs Hlavackova |
| 07 May 12 | r24 | Mutua Madrid Open Makarova vs Voskoboeva |
| 07 May 12 | r24 | Mutua Madrid Open Kvitova vs Erakovic |
| 07 May 12 | r24 | Mutua Madrid Open Safarova vs Kanepi |
| 07 May 12 | r24 | Mutua Madrid Open Errani vs Scheepers |
| 07 May 12 | r24 | Mutua Madrid Open Jankovic vs Suarez Navarro |
| 07 May 12 | r24 | Mutua Madrid Open Cetkovska vs Dominguez Lino |
| 07 May 12 | r24 | Mutua Madrid Open Kerber vs Williams |
| 07 May 12 | r24 | Mutua Madrid Open Li vs Soler Espinosa |
| 07 May 12 | r24 | Mutua Madrid Open Stosur vs Mchale |
| 08 May 12 | r24 | Mutua Madrid Open Sharapova vs Zakopalova |
| 08 May 12 | r24 | Mutua Madrid Open Azarenka vs Hlavackova |
| 08 May 12 | r24 | Mutua Madrid Open Ivanovic vs Petrova |
| 08 May 12 | r24 | Mutua Madrid Open Safarova vs Suarez Navarro |
| 08 May 12 | r24 | Mutua Madrid Open Peer vs Lepchenko |
| 08 May 12 | r24 | Mutua Madrid Open Medina Garrigues vs Cirstea |
| 08 May 12 | r24 | Mutua Madrid Open Wozniacki vs Barthel |
| 08 May 12 | r24 | Mutua Madrid Open Williams vs Pavlyuchenkova |
| 09 May 12 | r24 | Mutua Madrid Open Radwanska vs Errani |
| 09 May 12 | r24 | Mutua Madrid Open Vinci vs Wickmayer |
| 09 May 12 | r24 | Mutua Madrid Open Kirilenko vs Makarova |
| 09 May 12 | r24 | Mutua Madrid Open Kvitova vs Hradecka |
| 09 May 12 | r24 | Mutua Madrid Open Li vs Kerber |
| 09 May 12 | r24 | Mutua Madrid Open Stosur vs Cetkovska |
| 09 May 12 | r24 | Mutua Madrid Open Azarenka vs Ivanovic |
| 10 May 12 | r24 | Mutua Madrid Open Sharapova vs Safarova |
| 10 May 12 | r24 | Mutua Madrid Open Makarova vs Hradecka |
| 10 May 12 | r24 | Mutua Madrid Open Wozniacki vs Williams |
| 10 May 12 | r24 | Mutua Madrid Open Radwanska vs Vinci |
| 10 May 12 | r24 | Mutua Madrid Open Medina Garrigues vs Lepchenko |
| 11 May 12 | r24 | Mutua Madrid Open Azarenka vs Li |
| 11 May 12 | r24 | Mutua Madrid Open Sharapova vs Williams |
| 11 May 12 | r24 | Mutua Madrid Open Radwanska vs Lepchenko |
| 11 May 12 | r24 | Mutua Madrid Open Stosur vs Hradecka |
| 12 May 12 | r24 | Mutua Madrid Open Azarenka vs Radwanska |
| 12 May 12 | r24 | Mutua Madrid Open Williams vs Hradecka |
| 13 May 12 | r24 | Mutua Madrid Open Azarenka vs Williams |
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