| 17 May 22 | r05     | Caracas F.C.Caracas F.C. | 0 - 0 | The StrongestThe Strongest |
| 17 May 22 | r05 | BragantinoBragantino | 0 - 1 | Estudiantes de la PlataEstudiantes d |
| 17 May 22 | r05 | PeñarolPeñarol | 0 - 0 | Cerro PorteñoCerro Porteño |
| 18 May 22 | r05 | Boca JuniorsBoca Juniors | 1 - 1 | CorinthiansCorinthians |
| 18 May 22 | r05 | FlamengoFlamengo | 3 - 0 | Universidad CatólicaUniversidad C |
| 18 May 22 | r05 | Sporting CristalSporting Cris | 0 - 0 | Talleres de CordobaTalleres de C |
| 18 May 22 | r05 | PalmeirasPalmeiras | 1 - 0 | EmelecEmelec |
| 18 May 22 | r05 | Atletico PRAtletico PR | 2 - 0 | Club LibertadClub Libertad |
| 18 May 22 | r05 | Nacional MontevideoNacional Mont | 2 - 3 | Velez SarsfieldVelez Sarsfie |
| 19 May 22 | r05 | ColonColon | 2 - 1 | Club OlimpiaClub Olimpia |
| 19 May 22 | r05 | Deportivo Táchira F.C.Deportivo Tác | 3 - 0 | Independiente PetroleroIndependiente |
| 19 May 22 | r05 | Deportes TolimaDeportes Toli | 2 - 2 | America MGAmerica MG |
| 19 May 22 | r05 | Alianza LimaAlianza Lima | 0 - 2 | FortalezaFortaleza |
| 19 May 22 | r05 | Atletico MGAtletico MG | 3 - 1 | Independiente del ValleIndependiente |
| 20 May 22 | r05  | River PlateRiver Plate | 4 - 0 | Colo-ColoColo-Colo |
| 20 May 22 | r05 | Deportivo CaliDeportivo Cal | 3 - 0 | Always ReadyAlways Ready |
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