| 18 May 21 | r05     | PalmeirasPalmeiras | 3 - 4 | Defensa y JusticiaDefensa y Jus |
| 18 May 21 | r05 | The StrongestThe Strongest | 2 - 1 | Santos FCSantos FC |
| 18 May 21 | r05 | Nacional MontevideoNacional Mont | 1 - 0 | Universidad CatólicaUniversidad C |
| 19 May 21 | r05 | UniversitarioUniversitario | 3 - 2 | Independiente del ValleIndependiente |
| 19 May 21 | r05 | FluminenseFluminense | 1 - 2 | Atlético JuniorAtlético Juni |
| 19 May 21 | r05 | Sao PauloSao Paulo | 0 - 1 | Racing ClubRacing Club |
| 19 May 21 | r05 | Sporting CristalSporting Cris | 2 - 0 | RentistasRentistas |
| 19 May 21 | r05 | Velez SarsfieldVelez Sarsfie | 2 - 1 | Unión La CaleraUnión La Cale |
| 20 May 21 | r05 | River PlateRiver Plate | 2 - 1 | Independiente Santa FeIndependiente |
| 20 May 21 | r05 | FlamengoFlamengo | 2 - 2 | LDU QuitoLDU Quito |
| 20 May 21 | r05  | Cerro PorteñoCerro Porteño | 0 - 1 | Atletico MGAtletico MG |
| 20 May 21 | r05 | Deportivo Táchira F.C.Deportivo Tác | 7 - 2 | Always ReadyAlways Ready |
| 20 May 21 | r05 | América de CaliAmérica de Ca | 3 - 1 | Real Esppor ClubReal Esppor C |
| 20 May 21 | r05 | Argentinos JuniorsArgentinos Ju | 1 - 0 | Atlético NacionalAtlético Naci |
| 21 May 21 | r05 | Club OlimpiaClub Olimpia | 0 - 1 | InternacionalInternacional |
| 21 May 21 | r05 | Boca JuniorsBoca Juniors | 0 - 0 | Barcelona SCBarcelona SC |
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