| 06 Jun 16 | r35  |  Mercedes Cup Marchenko vs Groth |
| 06 Jun 16 | r35 | Mercedes Cup Jaziri vs Berrer |
| 07 Jun 16 | r35 | Mercedes Cup Troicki vs Mayer |
| 07 Jun 16 | r35 | Mercedes Cup Martin vs Fritz |
| 07 Jun 16 | r35 | Mercedes Cup Istomin vs Stepanek |
| 07 Jun 16 | r35 | Mercedes Cup Pouille vs Millman |
| 07 Jun 16 | r35 | Mercedes Cup Kudla vs Lajovic |
| 07 Jun 16 | r35 | Mercedes Cup Dimitrov vs Del Potro |
| 07 Jun 16 | r35 | Mercedes Cup Lopez vs Youzhny |
| 07 Jun 16 | r35 | Mercedes Cup Kohlschreiber vs Herbert |
| 07 Jun 16 | r35 | Mercedes Cup Stakhovsky vs Choinski |
| 07 Jun 16 | r35 | Mercedes Cup Baghdatis vs Struff |
| 08 Jun 16 | r35 | Mercedes Cup Berrer vs Mayer |
| 08 Jun 16 | r35 | Mercedes Cup Kohlschreiber vs Kudla |
| 09 Jun 16 | r35 | Mercedes Cup Thiem vs Groth |
| 09 Jun 16 | r35 | Mercedes Cup Simon vs Struff |
| 09 Jun 16 | r35 | Mercedes Cup Youzhny vs Stakhovsky |
| 09 Jun 16 | r35 | Mercedes Cup Federer vs Fritz |
| 09 Jun 16 | r35 | Mercedes Cup Cilic vs Stepanek |
| 09 Jun 16 | r35 | Mercedes Cup Millman vs Del Potro |
| 10 Jun 16 | r35 | Mercedes Cup Thiem vs Youzhny |
| 10 Jun 16 | r35 | Mercedes Cup Federer vs Mayer |
| 10 Jun 16 | r35 | Mercedes Cup Kohlschreiber vs Stepanek |
| 10 Jun 16 | r35 | Mercedes Cup Simon vs Del Potro |
| 11 Jun 16 | r35 | Mercedes Cup Federer vs Thiem |
| 11 Jun 16 | r35 | Mercedes Cup Kohlschreiber vs Del Potro |
| 12 Jun 16 | r35 | Mercedes Cup Thiem vs Kohlschreiber |
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