| 15 Feb 16 | r15  |  Rio Open Isner vs Pella |
| 16 Feb 16 | r15 | Rio Open Cervantes vs Daniel |
| 16 Feb 16 | r15 | Rio Open Giraldo vs Elias |
| 16 Feb 16 | r15 | Rio Open Ramos Vinolas vs Lajovic |
| 16 Feb 16 | r15 | Rio Open Schwartzman vs Souza |
| 16 Feb 16 | r15 | Rio Open Sock vs Delbonis |
| 16 Feb 16 | r15 | Rio Open Lorenzi vs Cecchinato |
| 16 Feb 16 | r15 | Rio Open Fognini vs Bedene |
| 16 Feb 16 | r15 | Rio Open Thiem vs Andujar |
| 16 Feb 16 | r15 | Rio Open Ferrer vs Jarry |
| 16 Feb 16 | r15 | Rio Open Bellucci vs Dolgopolov |
| 16 Feb 16 | r15 | Rio Open Monaco vs Gimeno Traver |
| 16 Feb 16 | r15 | Rio Open Cuevas vs Bagnis |
| 16 Feb 16 | r15 | Rio Open Almagro vs Munoz De La Nava |
| 16 Feb 16 | r15 | Rio Open Nadal vs Carreno Busta |
| 17 Feb 16 | r15 | Rio Open Tsonga vs Monteiro |
| 17 Feb 16 | r15 | Rio Open Thiem vs Schwartzman |
| 17 Feb 16 | r15 | Rio Open Fognini vs Gimeno Traver |
| 18 Feb 16 | r15 | Rio Open Pella vs Giraldo |
| 18 Feb 16 | r15 | Rio Open Ferrer vs Ramos Vinolas |
| 18 Feb 16 | r15 | Rio Open Dolgopolov vs Cervantes |
| 18 Feb 16 | r15 | Rio Open Delbonis vs Lorenzi |
| 18 Feb 16 | r15 | Rio Open Nadal vs Almagro |
| 18 Feb 16 | r15 | Rio Open Cuevas vs Monteiro |
| 19 Feb 16 | r15 | Rio Open Pella vs Gimeno Traver |
| 19 Feb 16 | r15 | Rio Open Cuevas vs Delbonis |
| 19 Feb 16 | r15 | Rio Open Nadal vs Dolgopolov |
| 20 Feb 16 | r15 | Rio Open Ferrer vs Thiem |
| 20 Feb 16 | r15 | Rio Open Thiem vs Pella |
| 21 Feb 16 | r15 | Rio Open Nadal vs Cuevas |
| 21 Feb 16 | r15 | Rio Open Cuevas vs Pella |
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