| 20 Oct 14 | r62  |  Valencia Open 500 Garcia Lopez vs Lu |
| 20 Oct 14 | r62 | Valencia Open 500 Granollers vs Carreno Busta |
| 20 Oct 14 | r62 | Valencia Open 500 Klizan vs Kozlov |
| 21 Oct 14 | r62 | Valencia Open 500 Isner vs Robredo |
| 21 Oct 14 | r62 | Valencia Open 500 Sousa vs Lajovic |
| 21 Oct 14 | r62 | Valencia Open 500 Lopez vs Gombos |
| 21 Oct 14 | r62 | Valencia Open 500 Simon vs Dolgopolov |
| 21 Oct 14 | r62 | Valencia Open 500 Chardy vs Jaziri |
| 21 Oct 14 | r62 | Valencia Open 500 Mayer vs Verdasco |
| 21 Oct 14 | r62 | Valencia Open 500 Anderson vs Kohlschreiber |
| 21 Oct 14 | r62 | Valencia Open 500 Fognini vs Ramos Vinolas |
| 22 Oct 14 | r62 | Valencia Open 500 Berdych vs Andujar |
| 22 Oct 14 | r62 | Valencia Open 500 Youzhny vs Bellucci |
| 22 Oct 14 | r62 | Valencia Open 500 Murray vs Melzer |
| 22 Oct 14 | r62 | Valencia Open 500 Bautista vs Giraldo |
| 22 Oct 14 | r62 | Valencia Open 500 Ferrer vs Seppi |
| 22 Oct 14 | r62 | Valencia Open 500 Lopez vs Carreno Busta |
| 22 Oct 14 | r62 | Valencia Open 500 Robredo vs Lu |
| 23 Oct 14 | r62 | Valencia Open 500 Anderson vs Klizan |
| 23 Oct 14 | r62 | Valencia Open 500 Andujar vs Lajovic |
| 23 Oct 14 | r62 | Valencia Open 500 Dolgopolov vs Chardy |
| 23 Oct 14 | r62 | Valencia Open 500 Murray vs Fognini |
| 23 Oct 14 | r62 | Valencia Open 500 Bautista vs Bellucci |
| 23 Oct 14 | r62 | Valencia Open 500 Ferrer vs Verdasco |
| 24 Oct 14 | r62 | Valencia Open 500 Murray vs Anderson |
| 24 Oct 14 | r62 | Valencia Open 500 Ferrer vs Bellucci |
| 24 Oct 14 | r62 | Valencia Open 500 Chardy vs Carreno Busta |
| 24 Oct 14 | r62 | Valencia Open 500 Robredo vs Andujar |
| 25 Oct 14 | r62 | Valencia Open 500 Ferrer vs Murray |
| 25 Oct 14 | r62 | Valencia Open 500 Robredo vs Chardy |
| 26 Oct 14 | r62 | Valencia Open 500 Murray vs Robredo |
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