| 24 Feb 14 | r18  |  Brasil Open Mayer vs Pella |
| 24 Feb 14 | r18 | Brasil Open Haase vs Souza |
| 25 Feb 14 | r18 | Brasil Open Zeballos vs Cuevas |
| 25 Feb 14 | r18 | Brasil Open Montanes vs Bedene |
| 25 Feb 14 | r18 | Brasil Open Delbonis vs Volandri |
| 25 Feb 14 | r18 | Brasil Open Reister vs Haider Maurer |
| 25 Feb 14 | r18 | Brasil Open Garcia Lopez vs Dutra Silva |
| 25 Feb 14 | r18 | Brasil Open Lorenzi vs Riba |
| 25 Feb 14 | r18 | Brasil Open Klizan vs Clezar |
| 25 Feb 14 | r18 | Brasil Open Gonzalez vs Starace |
| 25 Feb 14 | r18 | Brasil Open Giraldo vs Bellucci |
| 25 Feb 14 | r18 | Brasil Open Ramos vs Elias |
| 26 Feb 14 | r18 | Brasil Open Pella vs Zeballos |
| 26 Feb 14 | r18 | Brasil Open Almagro vs Delbonis |
| 26 Feb 14 | r18 | Brasil Open Montanes vs Souza |
| 26 Feb 14 | r18 | Brasil Open Haas vs Starace |
| 27 Feb 14 | r18 | Brasil Open Monaco vs Ramos |
| 27 Feb 14 | r18 | Brasil Open Lorenzi vs Dutra Silva |
| 27 Feb 14 | r18 | Brasil Open Klizan vs Granollers |
| 27 Feb 14 | r18 | Brasil Open Bellucci vs Haider Maurer |
| 28 Feb 14 | r18 | Brasil Open Monaco vs Lorenzi |
| 28 Feb 14 | r18 | Brasil Open Delbonis vs Montanes |
| 28 Feb 14 | r18 | Brasil Open Haas vs Zeballos |
| 01 Mar 14 | r18 | Brasil Open Klizan vs Bellucci |
| 01 Mar 14 | r18 | Brasil Open Haas vs Lorenzi |
| 01 Mar 14 | r18 | Brasil Open Delbonis vs Bellucci |
| 02 Mar 14 | r18 | Brasil Open Delbonis vs Lorenzi |
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