| 17 Feb 14 | r15  |  Rio Open Garcia Lopez vs Klizan |
| 17 Feb 14 | r15 | Rio Open Volandri vs Lajovic |
| 17 Feb 14 | r15 | Rio Open Souza vs Bagnis |
| 18 Feb 14 | r15 | Rio Open Giraldo vs Bellucci |
| 18 Feb 14 | r15 | Rio Open Delbonis vs Clezar |
| 18 Feb 14 | r15 | Rio Open Andujar vs Reister |
| 18 Feb 14 | r15 | Rio Open Almagro vs Dolgopolov |
| 18 Feb 14 | r15 | Rio Open Mayer vs Ramos |
| 18 Feb 14 | r15 | Rio Open Sousa vs Granollers |
| 18 Feb 14 | r15 | Rio Open Robredo vs Carreno Busta |
| 18 Feb 14 | r15 | Rio Open Monaco vs Zeballos |
| 18 Feb 14 | r15 | Rio Open Gonzalez vs Cuevas |
| 18 Feb 14 | r15 | Rio Open Fognini vs Bedene |
| 18 Feb 14 | r15 | Rio Open Ferrer vs Chardy |
| 18 Feb 14 | r15 | Rio Open Nadal vs Gimeno Traver |
| 19 Feb 14 | r15 | Rio Open Haase vs Montanes |
| 19 Feb 14 | r15 | Rio Open Andujar vs Klizan |
| 19 Feb 14 | r15 | Rio Open Robredo vs Lajovic |
| 19 Feb 14 | r15 | Rio Open Monaco vs Bellucci |
| 20 Feb 14 | r15 | Rio Open Ferrer vs Delbonis |
| 20 Feb 14 | r15 | Rio Open Dolgopolov vs Bagnis |
| 20 Feb 14 | r15 | Rio Open Fognini vs Cuevas |
| 20 Feb 14 | r15 | Rio Open Nadal vs Montanes |
| 21 Feb 14 | r15 | Rio Open Sousa vs Ramos |
| 21 Feb 14 | r15 | Rio Open Fognini vs Dolgopolov |
| 21 Feb 14 | r15 | Rio Open Ferrer vs Bellucci |
| 21 Feb 14 | r15 | Rio Open Robredo vs Andujar |
| 22 Feb 14 | r15 | Rio Open Nadal vs Sousa |
| 22 Feb 14 | r15 | Rio Open Ferrer vs Dolgopolov |
| 22 Feb 14 | r15 | Rio Open Nadal vs Andujar |
| 23 Feb 14 | r15 | Rio Open Nadal vs Dolgopolov |
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